Dissolved load is the portion of a

stream A stream is a continuous body of water, body of surface water Current (stream), flowing within the stream bed, bed and bank (geography), banks of a channel (geography), channel. Depending on its location or certain characteristics, a stream ...

's total sediment load that is carried in

solution Solution may refer to: * Solution (chemistry), a mixture where one substance is dissolved in another * Solution (equation), in mathematics ** Numerical solution, in numerical analysis, approximate solutions within specified error bounds * Soluti ...

, especially

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

s from

chemical weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement ...

. It is a major contributor to the total amount of material removed from a river's

drainage basin A drainage basin is an area of land where all flowing surface water converges to a single point, such as a river mouth, or flows into another body of water, such as a lake or ocean. A basin is separated from adjacent basins by a perimeter, t ...

, along with suspended load and

bed load The term bed load or bedload describes particles in a flowing fluid (usually water) that are transported along the stream bed. Bed load is complementary to suspended load and wash load. Bed load moves by rolling, sliding, and/or saltating (h ...

. The amount of material carried as dissolved load is typically much smaller than the suspended load, though this is not always the case, particularly when the available river flow is mostly harnessed for purposes such as

irrigation Irrigation (also referred to as watering) is the practice of applying controlled amounts of water to land to help grow Crop, crops, Landscape plant, landscape plants, and Lawn, lawns. Irrigation has been a key aspect of agriculture for over 5,00 ...

or industrial uses. Dissolved load comprises a significant portion of the total material flux out of a landscape, and its composition is important in regulating the chemistry and biology of the stream water. Stream Load

The dissolved load is primarily controlled by the rate of

, which depends on

climate Climate is the long-term weather pattern in an area, typically averaged over 30 years. More rigorously, it is the mean and variability of meteorological variables over a time spanning from months to millions of years. Some of the meteorologi ...

and

weather Weather is the state of the atmosphere, describing for example the degree to which it is hot or cold, wet or dry, calm or stormy, clear or cloudy. On Earth, most weather phenomena occur in the lowest layer of the planet's atmosphere, the ...

conditions such as

moisture Moisture is the presence of a liquid, especially water, often in trace amounts. Small amounts of water may be found, for example, in the air (humidity), in foods, and in some commercial products. Moisture also refers to the amount of water vapo ...

and

temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measurement, measured with a thermometer. Thermometers are calibrated in various Conversion of units of temperature, temp ...

. Dissolved load has many useful applications within the field of

geology Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other Ear ...

, including

erosion Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust, and then transports it to another location where it is deposited. Erosion is distin ...

denudation Denudation is the geological processes in which moving water, ice, wind, and waves erode the Earth's surface, leading to a reduction in elevation and in relief of landforms and landscapes. Although the terms erosion and denudation are used interc ...

, and reconstructing climate in the past.

Measurement techniques

Dissolved load is typically measured by taking samples of water from a river and running various scientific tests on them. First, the pH,

conductivity Conductivity may refer to: *Electrical conductivity, a measure of a material's ability to conduct an electric current **Conductivity (electrolytic), the electrical conductivity of an electrolyte in solution ** Ionic conductivity (solid state), ele ...

, and

bicarbonate In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogencarbonate) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula . Bicarbonate serves a crucial biochem ...

alkalinity Alkalinity (from ar, القلوي, al-qaly, lit=ashes of the saltwort) is the capacity of water to resist acidification. It should not be confused with basicity, which is an absolute measurement on the pH scale. Alkalinity is the strength ...

of the sample are measured. Next, samples are filtered to remove any suspended

sediments Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity In physics, gravity () is a fundame ...

and preserved with

chloroform Chloroform, or trichloromethane, is an organic compound with chemical formula, formula Carbon, CHydrogen, HChlorine, Cl3 and a common organic solvent. It is a colorless, strong-smelling, dense liquid produced on a large scale as a precursor to ...

to prevent growth of microorganisms, while the others are acidified with

hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid Acid strength is the tendency of an acid, symbol ...

added to keep dissolved ions from

precipitating In an aqueous solution, precipitation is the process of transforming a dissolved chemical substance, substance into an insoluble solid from a Supersaturated solution, super-saturated solution. The solid formed is called the precipitate. In cas ...

out of solution. Then, various chemical tests were applied to determine the concentration of each

solute In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent ...

. For example, the concentrations of

sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...

and

potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...

ions can be determined by flame photometry, while the

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...

and

magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...

ion concentrations can be determined by

atomic absorption spectrophotometry Atomic absorption spectroscopy (AAS) and atomic emission spectroscopy (AES) is a spectroanalytical procedure for the quantitative determination of chemical elemlight) by free atoms in the gaseous state. Atomic absorption spectroscopy is based o ...

Applications

Reconstructing climate

Dissolved load can provide valuable information about the rate of

soil formation Soil formation, also known as pedogenesis, is the process of soil genesis as regulated by the effects of place, environment, and history. Biogeochemical processes act to both create and destroy order (anisotropy) within soils. These alterations l ...

and other processes of chemical

. In particular, the mass balance between the dissolved load and solid phase is helpful in determining surface dynamics. In addition, dissolved load can be used to reconstruct the climate of the Earth in the past. This is because chemical weathering is the major contributor to the dissolved load of a stream. The chemical weathering of silicate rocks is the primary sink for

carbon dioxide Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...

in the atmosphere, because atmospheric carbon dioxide is converted into

carbonate rocks Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and dolomite rock (also known as doloston ...

in the

carbonate–silicate cycle The carbonate–silicate geochemical cycle, also known as the inorganic carbon cycle, describes the long-term transformation of silicate rocks to carbonate rocks by weathering and sedimentation, and the transformation of carbonate rocks back int ...

. Carbon dioxide concentrations are the primary control of the

greenhouse effect The greenhouse effect is a process that occurs when energy from a planet's host star goes through the planet's atmosphere and heats the planet's surface, but greenhouse gases in the atmosphere prevent some of the heat from returning directly ...

, which determines the temperature of the Earth.

Denudation

Denudation Denudation is the geological processes in which moving water, ice, wind, and waves erode the Earth's surface, leading to a reduction in elevation and in relief of landforms and landscapes. Although the terms erosion and denudation are used interc ...

is the process of wearing away the top layers of Earth's landscape. Because the rate of denudation is normally too small to directly measure, it can be indirectly determined by measuring the sediment load of the streams that drain the area in question. This is possible because any material that passes through a certain point on a stream is guaranteed to have come from somewhere in the stream's

upstream of that point. As

topographic relief Terrain or relief (also topographical relief) involves the vertical and horizontal dimensions of land surface. The term bathymetry is used to describe underwater relief, while hypsometry studies terrain relative to sea level. The Latin w ...

increases, the dissolved load's contribution to the total stream load decreases due to the fact that on steeper surfaces, rain is less likely to infiltrate the rocks, leading to less chemical weathering, which decreases the dissolved load.

Salt export

The process of carrying

salts In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively c ...

by water to the sea or a land-locked lake from a river basin is called salt export. When adequate salt export is not occurring, the river basin area gradually converts into

saline soils Soil salinity is the salt content in the soil; the process of increasing the salt content is known as salinization. Salts occur naturally within soils and water. Salination can be caused by natural processes such as mineral weathering or by the ...

and/or

alkali soil Alkali, or Alkaline, soils are clay soils with high pH (greater than 8.5), a poor soil structure and a low infiltration capacity. Often they have a hard calcareous layer at 0.5 to 1 metre depth. Alkali soils owe their unfavorable physico ...

s, particularly in lower reaches.

Dissolved loads of selected major rivers

References

USGS CMG InfoBank: Suspended and Dissolved Loads
{{Rivers, streams and springs Geochemistry Hydrology Weathering Geomorphology